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(D) The reaction of benzoic acid $(C_6H_5COOH)$ with $Br_2$ in the presence of $Fe$ (dark) is an electrophilic aromatic substitution. The $-COOH$ grou

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m-bromobenzoic acid,p-bromotoluene

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(D) The reaction of benzoic acid $(C_6H_5COOH)$ with $Br_2$ in the presence of $Fe$ (dark) is an electrophilic aromatic substitution. The $-COOH$ group is a deactivating and meta-directing group,so the major product $X$ is $m$-bromobenzoic acid.The reaction of toluene $(C_6H_5CH_3)$ with $Br_2$ in the presence of $Fe$ (dark) is also an electrophilic aromatic substitution. The $-CH_3$ group is an activating and ortho/para-directing group. Due to steric hindrance at the ortho position,the major product $Y$ is $p$-bromotoluene.Therefore,the major products are $m$-bromobenzoic acid and $p$-bromotoluene.

What are the major products $X$ and $Y$ respectively in the following set of reactions?

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