What is the number of moles of ionisable Cl^{ | vedclass

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Question

(B) The reaction of a coordination complex with excess silver nitrate $(AgNO_3)$ precipitates the ionisable chloride ions as silver chloride $(AgCl)$.

Vedclass · Accepted Answer

$2$

Vedclass · Answer

(B) The reaction of a coordination complex with excess silver nitrate $(AgNO_3)$ precipitates the ionisable chloride ions as silver chloride $(AgCl)$.According to the stoichiometry of the reaction:$[M(X)_n]Cl_2 + 2AgNO_3 \rightarrow [M(X)_n](NO_3)_2 + 2AgCl$Since $1 \ mole$ of the complex reacts to form $2 \ moles$ of $AgCl$,it indicates that there are $2 \ moles$ of ionisable $Cl^{-}$ ions present outside the coordination sphere.

What is the number of moles of ionisable $Cl^{-}$ ions in a coordination complex if it forms $2 \ moles$ of $AgCl$ when treated with silver nitrate solution in excess?

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