What is the time required for $99 \%$ completion of a first order reaction if the rate constant is $23.03 \ min^{-1}$?

$A$ reaction has a rate constant $k = 2.4 \times 10^{-4} \ s^{-1}$. Find the ratio of $t_{99.9}$ to $t_{50}$.

For the decomposition of $N_2O_5$ according to the equation $2N_2O_5(g) \to 4NO_2(g) + O_2(g)$,the reaction is of first order. After $30 \, \min$ from the start of the reaction in a closed vessel,the total pressure is $305.5 \, mm \, Hg$,and at the end of complete decomposition,the total pressure is $587.5 \, mm \, Hg$. Calculate the rate constant of the reaction.

The reaction $2N_2O_5 \,(g) \to 4NO_2 \,(g) + O_2 \,(g)$ follows first order kinetics. The pressure of a vessel containing only $N_2O_5$ was found to increase from $50 \, mmHg$ to $87.5 \, mmHg$ in $30 \, min$. The pressure exerted by the gases after $60 \, min$ will be .......... $mmHg$ (assume temperature remains constant).

In a first order reaction,the concentration of the reactant is reduced to $(1/8)^{th}$ of its initial concentration in $23.03 \ min$. What is the half-life period of the reaction (in $min$)?

The rate constant and half-life of a first-order reaction are related to each other as -