What is threshold energy?

  • A
    The minimum energy that colliding molecules must possess for a chemical reaction to occur.
  • B
    The energy required to break a chemical bond.
  • C
    The energy released during a chemical reaction.
  • D
    The maximum energy of the reactants.

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Catalysts are used to increase the rate of a chemical reaction. Because it

Consider $A \xrightarrow{k_1} B$ and $C \xrightarrow{k_2} D$ are two reactions. If the rate constant $(k_1)$ of the $A \rightarrow B$ reaction can be expressed by the following equation $\log_{10} k = 14.34 - \frac{1.5 \times 10^4}{T/K}$ and activation energy of $C \rightarrow D$ reaction $(Ea_2)$ is $\frac{1}{5}$th of the $A \rightarrow B$ reaction $(Ea_1)$, then the value of $(Ea_2)$ is . . . . . . $kJ \ mol^{-1}$. (Nearest Integer)

The decomposition of ethane,$\frac{d[C_2H_6]}{dt} = k[C_2H_6]$,proceeds through a complex mechanism,which includes $5$ steps. The overall rate constant $(k)$ is expressed as $k = \frac{k_1 k_2 k_3}{k_2 k_5}$,where $k_1, k_2, k_3, k_4, k_5$ are the rate constants of the $5$ steps. If the activation energies of the steps are $E_1 = 1E, E_2 = 2E, E_3 = 3E, E_4 = 4E, E_5 = 5E$,where $E = 20 \ kJ/mol$,find the overall activation energy of the decomposition.

For the reaction,$aA + bB \rightarrow cC + dD$,the plot of $\log k$ vs $\frac{1}{T}$ is given below. The temperature at which the rate constant of the reaction is $10^{-4} \ s^{-1}$ is ............... $K$. (Rounded-off to the nearest integer) [Given: The rate constant of the reaction is $10^{-5} \ s^{-1}$ at $500 \ K$.]

The Arrhenius equation for the rate constant is $k = Ae^{-E_a/RT}$. $A$ chemical reaction will proceed more rapidly if there is a decrease in

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