What is denoted by a negative $E^o$ and a positive $E^o$ value in electrochemistry?

  • A
    Negative $E^o$ indicates a stronger reducing agent than $H_2$,while positive $E^o$ indicates a weaker reducing agent than $H_2$.
  • B
    Negative $E^o$ indicates a stronger oxidizing agent than $H_2$,while positive $E^o$ indicates a weaker oxidizing agent than $H_2$.
  • C
    Negative $E^o$ indicates a weaker reducing agent than $H_2$,while positive $E^o$ indicates a stronger reducing agent than $H_2$.
  • D
    Both indicate the same reducing strength.

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$Cr_2O_7^{2-} + I^{-} \to I_2 + Cr^{3+}$
$E^0_{cell} = 0.79 \ V$
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The $emf$ of a galvanic cell,with electrode potentials of silver $= +0.80 \ V$ and that of copper $= +0.34 \ V$,is ........... $V$.

Which of the following statements is false for $Hg$?

The standard reduction potentials at $298 \ K$ for the following half reactions are given against each:
$Zn^{2+}(aq.) + 2e^- \rightleftharpoons Zn_{(s)}$; $E^\circ = -0.762 \ V$
$Cr^{3+}(aq.) + 3e^- \rightleftharpoons Cr_{(s)}$; $E^\circ = -0.740 \ V$
$2H^{+}(aq.) + 2e^- \rightleftharpoons H_{2(g)}$; $E^\circ = 0.00 \ V$
$Fe^{3+}(aq.) + e^- \rightleftharpoons Fe^{2+}(aq.)$; $E^\circ = 0.770 \ V$
Which is the strongest reducing agent?

Aluminium displaces hydrogen from dilute $HCl$ whereas silver does not. The e.m.f. of a cell prepared by combining $Al/Al^{3+}$ and $Ag/Ag^{+}$ is $2.46 \ V$. The reduction potential of silver electrode is $+0.80 \ V$. The reduction potential of aluminium electrode is $........... \ V$.

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