When an acid cell is charged,then

Why is an external $emf$ of more than $2.2 \ V$ required for the extraction of $Cl_2$ from brine?

The $emf$ of the cell reaction is $1.1 \ V$. Calculate the free energy change for the reaction in $kJ$:
$Zn_{(s)} + Cu^{+2}_{(aq)} \longrightarrow Zn^{+2}_{(aq)} + Cu_{(s)}$

Match List-$I$ with List-$II$.

$LIST$-$I$ (Cell)	$LIST$-$II$ (Use/Property/Reaction)
$A$. Leclanche cell	$I$. Converts energy of combustion into electrical energy
$B$. Ni-Cd cell	$II$. Does not involve any ion in solution and is used in hearing aids
$C$. Fuel cell	$III$. Rechargeable
$D$. Mercury cell	$IV$. Reaction at anode $Zn \rightarrow Zn^{2+} + 2e^-$

Choose the correct answer from the options given below:

Give the anodic,cathodic,and overall reactions of a hydrogen-oxygen fuel cell.

Give the reactions for the following:
$(i)$ Reactions occurring at the electrodes and the overall redox reaction of a Daniell cell.
$(ii)$ Give the redox and electrode reactions of a $Cu-Ag$ galvanic cell.