When mercury $(II)$ chloride is treated with excess of stannous chloride,the products obtained are

$KMnO_4$ reacts with ferrous ammonium sulphate according to the equation
$MnO_4^- + 5Fe^{2+} + 8H^+ \to Mn^{2+} + 5Fe^{3+} + 4H_2O$
Here $10 \ mL$ of $0.1 \ M$ $KMnO_4$ is equivalent to:

Number of moles of $MnO_4^{-}$ required to oxidise one mole of ferrous oxalate completely in acidic medium will be $:-$ (in $mole$)

How do you account for the following observations?
$(a)$ Though alkaline potassium permanganate and acidic potassium permanganate both are used as oxidants,yet in the manufacture of benzoic acid from toluene,we use alcoholic potassium permanganate as an oxidant. Why? Write a balanced redox equation for the reaction.
$(b)$ When concentrated sulphuric acid is added to an inorganic mixture containing chloride,we get a colourless pungent-smelling gas $HCl$,but if the mixture contains bromide,then we get red vapour of bromine. Why?

Which of the following decolourises the colour of acidic $KMnO_4$?

Which of the following are non-metal displacement reactions?
$(A)$ $Ca_{(s)} + 2 H_2 O_{(l)} \longrightarrow Ca(OH)_{2(aq)} + H_{2(g)}$
$(B)$ $V_2 O_{5(s)} + 5 Ca_{(s)} \stackrel{\Delta}{\longrightarrow} 2 V_{(s)} + 5 CaO_{(s)}$
$(C)$ $2 Fe_{(s)} + 3 H_2 O_{(g)} \stackrel{\Delta}{\longrightarrow} Fe_2 O_{3(s)} + 3 H_{2(g)}$
$(D)$ $Cr_2 O_{3(s)} + 2 Al_{(s)} \stackrel{\Delta}{\longrightarrow} Al_2 O_{3(s)} + 2 Cr_{(s)}$