Which among the following is a false statement?

  • A
    Half life of a third order reaction is inversely proportional to the square of initial concentration of the reactant.
  • B
    Molecularity of a reaction may be zero or fractional.
  • C
    For a first order reaction $t_{1/2} = \frac{0.693}{K}$.
  • D
    Rate of zero order reaction is independent of initial concentration of reactant.

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For the reaction $NO_2 + CO \rightarrow CO_2 + NO$,the rate law is given as $\text{Rate} = K [NO_2]^2$. What is the number of $CO$ molecules participating in the slow step?

Assertion : In rate law,unlike in the expression for equilibrium constants,the exponents for concentrations do not necessarily match the stoichiometric coefficients.
Reason : It is the mechanism and not the balanced chemical equation for the overall change that governs the reaction rate.

$A$ study of chemical kinetics of the reaction $A + B \to$ Products,gave the following data at $25 \ ^oC$.
$Exp. \ No.$ $[A]$ $[B]$ $Rate$
$1.$ $1.0$ $0.15$ $4.2 \times 10^{-6}$
$2.$ $2.0$ $0.15$ $8.4 \times 10^{-6}$
$3.$ $1.0$ $0.20$ $5.6 \times 10^{-6}$

Find out the rate law.

What is the molecularity of a reaction? Explain its types with examples.

The rate of reaction at $273 \ K$ is $R_0$. The rate of reaction at $313 \ K$ will be (Assuming temperature coefficient equal to $2$).

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