Which among the following is an example of a metal-metal ion electrode?

  • A
    $Fe^{3+} (aq.), Fe^{2+} (aq.) \mid Pt$
  • B
    $Cl^{-} (aq.) \mid AgCl (s) \mid Ag$
  • C
    $Zn^{2+} (aq.) \mid Zn (s)$
  • D
    $OH^{-} (aq.) \mid O_{2} (g), Pt$

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What is the correct order of chemical reactivity with water according to the electrochemical series?

Assertion : If $\lambda^o_{Na^{+}}$ and $\lambda^o_{Cl^{-}}$ are molar limiting conductivity of sodium and chloride ions respectively,then the limiting molar conductivity for sodium chloride is given by the equation :
$\Lambda^o_{NaCl} = \lambda^o_{Na^{+}} + \lambda^o_{Cl^{-}}$
Reason : This is according to Kohlrausch law of independent migration of ions.

For the reaction $2 Fe^{3+}_{(aq)} + 2 I^{-}_{(aq)} \rightarrow 2 Fe^{2+}_{(aq)} + I_{2(s)}$,the magnitude of the standard molar free energy change,$\Delta_{r} G_{m}^{\circ} = -$ ........... $kJ$ (Round off to the Nearest Integer). $\left[ E_{Fe^{2+} / Fe_{(s)}}^{\circ} = -0.440 \ V; \ E_{Fe^{3+} / Fe_{(s)}}^{\circ} = -0.036 \ V; \ E_{I_{2} / 2I^{-}}^{\circ} = 0.539 \ V; \ F = 96500 \ C \ mol^{-1} \right]$

Fill in the blanks :
$1.$ $E_{cell}^o$ of Daniell cell $= $ ........... .
$2.$ In Daniell cell,$n = $ ........... .
$3.$ For $Al + 3Ag^{+} \rightarrow Al^{3+} + 3Ag,$ $n = $ ...........

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Give the reactions for the following:
$(i)$ Reactions occurring at the electrodes and the overall redox reaction of a Daniell cell.
$(ii)$ Give the redox and electrode reactions of a $Cu-Ag$ galvanic cell.

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