Which is the best definition of “heat of neutralization”?
- AThe heat set free when one gram molecule of a base is neutralized by one gram molecule of an acid in dilute solution at a stated temperature.
- BThe heat absorbed when one gram molecule of an acid is neutralized by one gram molecule of a base in dilute solution at a stated temperature.
- CThe heat set free or absorbed when one gram atom of an acid is neutralized by one gram atom of a base at a stated temperature.
- DThe heat set free when one gram equivalent of an acid is neutralized by one gram equivalent of a base in dilute solution at a stated temperature.
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If $38.55 \ kJ$ of heat is absorbed when $6.0 \ g$ of $O_2$ reacts with $ClF$ according to the reaction $2ClF_{(g)} + O_{2(g)} \longrightarrow Cl_2O_{(g)} + OF_{2(g)}$. What is the standard enthalpy of reaction (in $kJ$)?
Using the data provided,calculate the bond energy $(kJ \ mol^{-1})$ of a $C \equiv C$ bond in $C_{2}H_{2}$. (Take the bond energy of a $C-H$ bond as $350 \ kJ \ mol^{-1}$)
$2C_{(s)} + H_{2(g)} \longrightarrow C_{2}H_{2(g)} \quad \Delta H = 225 \ kJ \ mol^{-1}$
$2C_{(s)} \longrightarrow 2C_{(g)} \quad \Delta H = 1410 \ kJ \ mol^{-1}$
$H_{2(g)} \longrightarrow 2H_{(g)} \quad \Delta H = 330 \ kJ \ mol^{-1}$
$2C_{(s)} + H_{2(g)} \longrightarrow C_{2}H_{2(g)} \quad \Delta H = 225 \ kJ \ mol^{-1}$
$2C_{(s)} \longrightarrow 2C_{(g)} \quad \Delta H = 1410 \ kJ \ mol^{-1}$
$H_{2(g)} \longrightarrow 2H_{(g)} \quad \Delta H = 330 \ kJ \ mol^{-1}$
The enthalpy change at $298 \ K$ for the decomposition of water is given in the following two steps:
Step $I$: $H_2O_{(g)} \to H_{(g)} + OH_{(g)}$; $\Delta H = 498 \ kJ \ mol^{-1}$
Step $II$: $OH_{(g)} \to H_{(g)} + O_{(g)}$; $\Delta H = 428 \ kJ \ mol^{-1}$
The average bond enthalpy of the $O-H$ bond is $.... \ kJ \ mol^{-1}$
Step $I$: $H_2O_{(g)} \to H_{(g)} + OH_{(g)}$; $\Delta H = 498 \ kJ \ mol^{-1}$
Step $II$: $OH_{(g)} \to H_{(g)} + O_{(g)}$; $\Delta H = 428 \ kJ \ mol^{-1}$
The average bond enthalpy of the $O-H$ bond is $.... \ kJ \ mol^{-1}$
Medium
View SolutionThe standard enthalpy of formation of $NH_3$ is $-46.0 \ kJ \ mol^{-1}.$ If the enthalpy of formation of $H_2$ from its atoms is $-436 \ kJ \ mol^{-1}$ and that of $N_2$ is $-712 \ kJ \ mol^{-1},$ the average bond enthalpy of $N-H$ bond in $NH_3$ is ................ $kJ \ mol^{-1}$
Calculate the heat of formation for propene $(C_3H_6)$ using the following thermochemical equations:
$(i) C_{(s)} + O_{2(g)} \to CO_{2(g)}; \Delta H_1 = -94.05 \ k.cal/mole$
$(ii) H_{2(g)} + \frac{1}{2} O_{2(g)} \to H_2O_{(l)}; \Delta H_2 = -68.32 \ k.cal/mole$
$(iii) C_3H_{6(g)} + \frac{9}{2} O_{2(g)} \to 3 CO_{2(g)} + 3 H_2O_{(l)}; \Delta H_3 = -499.7 \ k.cal/mole$
(Note: The original question provided propane combustion data; assuming propene combustion data for consistency).
$(i) C_{(s)} + O_{2(g)} \to CO_{2(g)}; \Delta H_1 = -94.05 \ k.cal/mole$
$(ii) H_{2(g)} + \frac{1}{2} O_{2(g)} \to H_2O_{(l)}; \Delta H_2 = -68.32 \ k.cal/mole$
$(iii) C_3H_{6(g)} + \frac{9}{2} O_{2(g)} \to 3 CO_{2(g)} + 3 H_2O_{(l)}; \Delta H_3 = -499.7 \ k.cal/mole$
(Note: The original question provided propane combustion data; assuming propene combustion data for consistency).
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