Which of the following aqueous solutions has the highest freezing point?

In cold countries,ethylene glycol is added to water in the radiators to:

$A$ solution of sucrose (molar mass $= 342 \, g \, mol^{-1}$) has been prepared by dissolving $68.5 \, g$ of sucrose in $1000 \, g$ of water. The freezing point of the solution obtained will be ......... $^oC$. ($K_f$ for water $= 1.86 \, K \, kg \, mol^{-1}$)

The normal freezing point $(f.p.)$ of nitrobenzene is $278.82 \ K$. If a non-volatile solute is dissolved in it and a solution of $0.25 \ molality$ is prepared,the observed freezing point of the solution is $276.82 \ K$. Evaluate the cryoscopic constant $(K_f)$ of nitrobenzene in $K \ kg \ mol^{-1}$.

The freezing point depression constant $(K_{f})$ of benzene is $5.12 \ K \ kg \ mol^{-1}$. The freezing point depression for the solution of molality $0.078 \ m$ containing a non-electrolyte solute in benzene is..........$K$ (rounded off up to two decimal places).

Freezing point of a $4 \%$ aqueous solution of $X$ is equal to the freezing point of a $12 \%$ aqueous solution of $Y$. If the molecular weight of $X$ is $A$,then the molecular weight of $Y$ is ............. $A$.