Which of the following can act both as an oxidizing and a reducing agent?

$6 \times 10^{-3} \text{ mole}$ of $K_2Cr_2O_7$ reacts completely with $9 \times 10^{-3} \text{ mole}$ of $X^{n+}$ to give $XO_3^-$ and $Cr^{3+}$. The value of $n$ is:

Thiosulphate reacts differently with iodine and bromine in the reactions given below:
$2 S_2 O_3^{2-} + I_2 \rightarrow S_4 O_6^{2-} + 2 I^{-}$
$S_2 O_3^{2-} + 4 Br_2 + 5 H_2 O \rightarrow 2 SO_4^{2-} + 8 Br^{-} + 10 H^{+}$
Which of the following statements justifies the above dual behaviour of thiosulphate?

Which of the following reactions is not a redox reaction?

Assign $A, B, C, D$ from the given type of reaction.
$PbCrO_4 \downarrow + 4NaOH \,(Excess) \longrightarrow Na_2[Pb(OH)_4] + Na_2CrO_4$

Assign $A$,$B$,$C$,$D$ from the given type of reaction.
$Na_2CO_3 + Pb(NO_3)_2 \longrightarrow PbCO_3 \downarrow + 2NaNO_3$