Which of the following cannot act as an oxidising agent?

Acidized $KMnO_4$ solution does not oxidise:

Consider the reactions:
$(a)$ $H_3PO_{2(aq)} + 4AgNO_{3(aq)} + 2H_2O_{(l)} \to H_3PO_{4(aq)} + 4Ag_{(s)} + 4HNO_{3(aq)}$
$(b)$ $H_3PO_{2(aq)} + 2CuSO_{4(aq)} + 2H_2O_{(l)} \to H_3PO_{4(aq)} + 2Cu_{(s)} + H_2SO_{4(aq)}$
$(c)$ $C_6H_5CHO_{(l)} + 2[Ag(NH_3)_2]^+_{(aq)} + 3OH^-_{(aq)} \to C_6H_5COO^-_{(aq)} + 2Ag_{(s)} + 4NH_{3(aq)} + 2H_2O_{(l)}$
$(d)$ $C_6H_5CHO_{(l)} + 2Cu^{2+}_{(aq)} + 5OH^-_{(aq)} \to$ No change observed.
What inference do you draw about the behaviour of $Ag^+$ and $Cu^{2+}$ from these reactions?

Bromine is liberated when an aqueous solution of potassium bromide is treated with

When heated in air,brown copper powder turns black. This black powder would turn brown again when heated with:

When acidified $K_2Cr_2O_7$ solution is added to $Sn^{2+}$ salts,then $Sn^{2+}$ changes to: