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(D) The Wurtz reaction involves the coupling of two alkyl halide molecules in the presence of $Na$ metal and dry ether to form a symmetric alkane. To

Vedclass · Accepted Answer

$CH_3-CH_2-CH_2-CH(Br)-CH_2-CH_3$

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(D) The Wurtz reaction involves the coupling of two alkyl halide molecules in the presence of $Na$ metal and dry ether to form a symmetric alkane. To form $4,5-$diethyloctane,the molecule must be split symmetrically at the bond between $C_4$ and $C_5$. The structure of $4,5-$diethyloctane is $CH_3-CH_2-CH_2-CH(C_2H_5)-CH(C_2H_5)-CH_2-CH_2-CH_3$. Splitting this gives two units of $CH_3-CH_2-CH_2-CH(Br)-CH_2-CH_3$ ($3$-bromohexane). Thus,the reaction is: $2CH_3-CH_2-CH_2-CH(Br)-CH_2-CH_3 + 2Na$ $\xrightarrow{	ext{dry ether}} CH_3-CH_2-CH_2-CH(C_2H_5)-CH(C_2H_5)-CH_2-CH_2-CH_3 + 2NaBr$.

Which of the following compounds will react with $Na$ to form $4,5-$diethyloctane?

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