Which of the following have the same number of unpaired electrons in $d$ orbitals?

Given below are two statements:
Statement $I$: The number of pairs among $[Ti^{4+}, V^{2+}], [V^{2+}, Mn^{2+}], [Mn^{2+}, Fe^{3+}]$ and $[V^{2+}, Cr^{2+}]$ in which both ions are coloured is $3$.
Statement $II$: The number of pairs among $[La^{3+}, Yb^{2+}], [Lu^{3+}, Ce^{4+}]$ and $[Ac^{3+}, Lr^{3+}]$ ions in which both are diamagnetic is $3$.
In the light of the above statements, choose the correct option from the options given below:

Which of the following statements are correct?
$(i)$ $V^{2+}$ liberates hydrogen from a dilute acid.
$(ii)$ The earlier members of the lanthanide series behave more like aluminium.
$(iii)$ The 'silver' $UK$ coins are made of $Cu/Ni$ alloy.
$(iv)$ The maximum oxidation state exhibited by Neptunium is $+7$.

Which of the following substances are colored even in the absence of $d-d$ transitions?

The transition metal used as a catalyst is

Which one is wrong in the following statements?