Which of the following is a non-ideal solution?

  • A
    Phenol + Aniline
  • B
    Benzene + Toluene
  • C
    n-hexane + n-heptane
  • D
    Bromoethane + Chloroethane

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Vapour pressure of pure acetone and chloroform at $328 \, K$ are $741.8 \, mm \, Hg$ and $632.8 \, mm \, Hg$ respectively. Assuming that they form an ideal solution over the entire range of composition,plot $p_{total}$,$p_{chloroform}$,and $p_{acetone}$ as a function of $x_{acetone}$. The experimental data observed for different compositions of the mixture is:
$100 \times x_{acetone}$$0, 11.8, 23.4, 36.0, 50.8, 85.2, 64.5, 72.1$
$p_{acetone} / mm \, Hg$$0, 54.9, 110.1, 202.4, 322.7, 405.9, 454.1, 521.1$
$p_{chloroform} / mm \, Hg$$632.8, 548.1, 469.4, 359.7, 257.7, 193.6, 161.2, 120.7$

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If liquids $A$ and $B$ form an ideal solution,then:

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