Which of the following is an oxidizing agent?

  • A
    $Mn(CO)_5$
  • B
    $Fe(CO)_5$
  • C
    $Mn_2(CO)_{10}$
  • D
    $Fe_2(CO)_9$

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Which of the following does not have a metal-carbon bond?

The number of sigma bonds in Ziese's salt,$[PtCl_3(C_2H_4)]^-$,is:

What are organometallic compounds? Explain in detail.

The correct statement$(s)$ regarding the binary transition metal carbonyl compounds is (are) (Atomic numbers: $Fe = 26, Ni = 28$)
$A$. Total number of valence shell electrons at metal centre in $Fe(CO)_5$ or $Ni(CO)_4$ is $16$
$B$. These are predominantly low spin in nature
$C$. Metal-carbon bond strengthens when the oxidation state of the metal is lowered
$D$. The carbonyl $C-O$ bond weakens when the oxidation state of the metal is increased

The correct statements about metal carbonyls are:
$A$. The metal-carbon bonds in metal carbonyls possess both $\sigma$ and $\pi$-character.
$B$. Due to synergic bonding interactions between metal and $CO$ ligand, the metal-carbon bond becomes weak.
$C$. The metal-carbon $\sigma$ bond is formed by the donation of a lone pair of electrons on the carbonyl carbon into a vacant orbital of metal.
$D$. The metal-carbon $\pi$ bond is formed by the donation of electrons from a filled $d$-orbital of metal into a vacant $\pi^*$ orbital of $CO$.
Choose the correct answer from the options given below:

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