Which of the following is incorrectly matched?

  • A
    $2(r^+ + r^-) = a$; For $NaCl$ type crystal
  • B
    Coordination number $= 12$; For $fcc$ unit cell
  • C
    $4r = \sqrt{2} \, a$; For $fcc$ unit cell
  • D
    $ZnS$ Crystal; Frenkel defect

Explore More

Similar Questions

Calculate the number of atoms present in $1.625 \text{ g}$ of a metal that forms a $bcc$ unit cell structure. Given: $[\rho \times a^3 = 3.25 \times 10^{-22} \text{ g}]$.

Atoms of metals $x$,$y$,and $z$ form face-centred cubic $(fcc)$ unit cell of edge length $L_x$,body-centred cubic $(bcc)$ unit cell of edge length $L_y$,and simple cubic unit cell of edge length $L_z$,respectively. If $r_z = \frac{\sqrt{3}}{2} r_y$; $r_y = \frac{8}{\sqrt{3}} r_x$; $M_z = \frac{3}{2} M_y$ and $M_z = 3 M_x$,then the correct statement$(s)$ is (are) [Given: $M_x$,$M_y$,and $M_z$ are molar masses of metals $x$,$y$,and $z$,respectively. $r_x$,$r_y$,and $r_z$ are atomic radii of metals $x$,$y$,and $z$,respectively.]
$(A)$ Packing efficiency of unit cell of $x >$ Packing efficiency of unit cell of $y >$ Packing efficiency of unit cell of $z$
$(B)$ $L_y > L_z$
$(C)$ $L_x > L_y$
$(D)$ Density of $x >$ Density of $y$

$CCP$ lattice of a solid made up of $B^{-}$ ions has an edge length of $3 \ \mathring{A}$ and a density of $5 \ g/cm^3$. If in this lattice $A^{+}$ ions are placed at alternate tetrahedral voids,then the percentage increase in density will be $............. \ \%$. [Molar mass of $A^{+} = 30 \ g/mol$,$N_A = 6 \times 10^{23}$]

Difficult
View Solution

The cubic unit cell structure of a compound containing cation $M$ and anion $X$ is shown below. When compared to the anion,the cation has a smaller ionic radius. Choose the correct statement$(s)$:
$(A)$ The empirical formula of the compound is $MX$.
$(B)$ The cation $M$ and anion $X$ have different coordination geometries.
$(C)$ The ratio of $M-X$ bond length to the cubic unit cell edge length is $0.866$.
$(D)$ The ratio of the ionic radii of cation $M$ to anion $X$ is $0.414$.

The halide of a metal $MX$ crystallizes in a $ccp$ structure ($NaCl$ type). If all the atoms situated at one of the tetrad axes are removed,what will be the simplest molecular formula of the halide?

Difficult
View Solution

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo