Which of the following is more basic than ani | vedclass

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(A) Benzylamine,$C_{6}H_{5}CH_{2}NH_{2}$,is more basic than aniline because the benzyl group $(C_{6}H_{5}CH_{2}-)$ is an electron-donating group due t

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Benzylamine

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(A) Benzylamine,$C_{6}H_{5}CH_{2}NH_{2}$,is more basic than aniline because the benzyl group $(C_{6}H_{5}CH_{2}-)$ is an electron-donating group due to the $+I$ effect. This increases the electron density on the nitrogen atom of the $-NH_{2}$ group,making the lone pair more available for donation. In contrast,phenyl and nitro groups are electron-withdrawing groups ($-I$ or $-M$ effects),which decrease the electron density on the nitrogen atom. Therefore,diphenylamine,triphenylamine,and $p-$nitroaniline are less basic than aniline.

Which of the following is more basic than aniline?

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