Which of the following mixtures is a non-ideal solution?

  • A
    Chlorobenzene and bromobenzene
  • B
    Benzene and toluene
  • C
    Chloroform and acetone
  • D
    Bromoethane and chloroethane

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In a binary ideal solution of liquids $A$ and $B$ at a constant temperature,the mole fraction of $B$ in the liquid phase is $0.4$ and in the vapor phase is $0.25$. If $P_B^o = 40 \ mm \ Hg$,then the vapor pressure of pure liquid $A$ at that temperature is .......... $mm \ Hg$.

Liquid $M$ and liquid $N$ form an ideal solution. The vapour pressures of pure liquids $M$ and $N$ are $450 \ mmHg$ and $700 \ mmHg,$ respectively at the same temperature. Then the correct statement is: ( $x_M =$ mole fraction of $M$ in solution; $x_N =$ mole fraction of $N$ in solution; $y_M =$ mole fraction of $M$ in vapour phase; $y_N =$ mole fraction of $N$ in vapour phase)

Vapour pressure of pure acetone and chloroform at $328 \, K$ are $741.8 \, mm \, Hg$ and $632.8 \, mm \, Hg$ respectively. Assuming that they form an ideal solution over the entire range of composition,plot $p_{total}$,$p_{chloroform}$,and $p_{acetone}$ as a function of $x_{acetone}$. The experimental data observed for different compositions of the mixture is:
$100 \times x_{acetone}$$0, 11.8, 23.4, 36.0, 50.8, 85.2, 64.5, 72.1$
$p_{acetone} / mm \, Hg$$0, 54.9, 110.1, 202.4, 322.7, 405.9, 454.1, 521.1$
$p_{chloroform} / mm \, Hg$$632.8, 548.1, 469.4, 359.7, 257.7, 193.6, 161.2, 120.7$

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$5$ moles of liquid $X$ and $10$ moles of liquid $Y$ make a solution having a vapour pressure of $70 \ torr$. The vapour pressures of pure $X$ and $Y$ are $63 \ torr$ and $78 \ torr$ respectively. Which of the following is true regarding the described solution?

Two liquids $x$ and $y$ form an ideal solution. At $300 \ K$,the vapor pressure of a solution containing $1 \ mol$ of $x$ and $3 \ mol$ of $y$ is $550 \ mm \ Hg$. At the same temperature,if $1 \ mol$ of $y$ is added to the solution,the vapor pressure increases by $10 \ mm \ Hg$. The vapor pressures of pure $x$ and $y$ are respectively:

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