Which of the following pairs is an example of | vedclass

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(D) Linkage isomerism occurs in coordination compounds containing ambidentate ligands,which can coordinate to the central metal atom through two diffe

Vedclass · Accepted Answer

$[Co(NO_2)(NH_3)_5]Cl_2$ and $[Co(ONO)(NH_3)_5]Cl_2$

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(D) Linkage isomerism occurs in coordination compounds containing ambidentate ligands,which can coordinate to the central metal atom through two different donor atoms.In the pair $[Co(NO_2)(NH_3)_5]Cl_2$ and $[Co(ONO)(NH_3)_5]Cl_2$,the ligand $NO_2^-$ is an ambidentate ligand.In the first complex,the nitrogen atom $(N)$ is the donor atom $(Co-NO_2)$,while in the second complex,the oxygen atom $(O)$ is the donor atom $(Co-ONO)$.Therefore,this pair represents linkage isomerism.

Which of the following pairs is an example of linkage isomerism?

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