Which of the following pairs of a chemical reaction is certain to result in a spontaneous reaction?

  • A
    Exothermic and decreasing disorder
  • B
    Endothermic and increasing disorder
  • C
    Exothermic and increasing disorder
  • D
    Endothermic and decreasing disorder

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For the change $H_2O_{(l)} \to H_2O_{(g)}$ at $P = 1 \ atm$ and $T = 373 \ K$,the free energy change $\Delta G = 0$. This indicates that:

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Under what conditions does a reaction always occur spontaneously?

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Calculate $\Delta H_f^o$ for $UBr_4$ from the $\Delta G^o$ of reaction and the $S^o$ values: $U_{(s)} + 2Br_2(\ell) \to UBr_{4(s)}$; $\Delta G^o = -788.6 \ kJ$; $S^o \ (J/K \cdot mol): U_{(s)} = 50.3, Br_2(\ell) = 152.3, UBr_{4(s)} = 242.6$.

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