Which of the following plots represent an exothermic reaction?

For a gaseous reversible reaction,the enthalpy of reaction at constant pressure is $1.8 \ Kcal/mol$ greater than that at constant volume at $300 \ K$. The value of $\left( \frac{K_P}{K_C} \right)$ for the reaction at $T = \left( \frac{1}{0.00821} \right) \ K$ is:

In a closed container of $1000\, cm^3$,$2\, mol$ of $PCl_5$,$2\, mol$ of $PCl_3$,and $3\, mol$ of $Cl_2$ are found to be at equilibrium at $27\, ^oC$. Then $K_P$ for the reaction $PCl_{5(g)} \rightleftharpoons PCl_{3(g)} + Cl_{2(g)}$ at $27\, ^oC$ is $.....$ $atm$.

For the reaction ${N_2}_{(g)} + {O_2}_{(g)} \rightleftharpoons 2NO_{(g)}$,the equilibrium constant ${K_C}$ is $4 \times 10^{-4}$ at temperature $T$. Calculate ${K_P}$.

For the reaction $2NOCl_{(g)} \rightleftharpoons 2NO_{(g)} + Cl_{2_{(g)}}$ at $1060 \ K$,the equilibrium constant $K_p$ is $0.033 \ atm$. Find the value of $K_c$. (Given $R = 0.082 \ L \ atm \ K^{-1} \ mol^{-1}$)

For the reaction $CO_{(g)} + Cl_{2(g)} \rightleftharpoons COCl_{2(g)}$,$\frac{K_p}{K_c}$ is equal to