Which of the following processes will release the maximum amount of heat to the surroundings when the volume is reduced to half of its initial value?

An insulating cylinder contains $4 \text{ moles}$ of an ideal diatomic gas. When a heat $Q$ is supplied to it, $2 \text{ moles}$ of the gas molecules dissociate. If the temperature of the gas remains constant, then the value of $Q$ is ($R$ - universal gas constant).

$N$ moles of an ideal diatomic gas are in a cylinder at temperature $T$. Suppose on supplying heat to the gas, its temperature remains constant but $n$ moles get dissociated into atoms. Heat supplied to the gas is

$1$ mole of rigid diatomic gas performs a work of $Q/5$ when heat $Q$ is supplied to it. The molar heat capacity of the gas during this transformation is $\frac{xR}{8}.$ The value of $x$ is $\ldots \ldots \ldots .$ $[R =$ universal gas constant $]$

Two cylinders $A$ and $B$ fitted with pistons contain equal amount of an ideal diatomic gas at $303 \text{ K}$. The piston of cylinder $A$ is free to move and that of cylinder $B$ is held fixed. The same amount of heat is given to the gas in each cylinder. If the rise in temperature of the gas in cylinder $B$ is $63 \text{ K}$, then the rise in temperature of the gas in $A$ is: (in $\text{ K}$)

$List-I$ describes thermodynamic processes in four different systems. $List-II$ gives the magnitudes (either exactly or as a close approximation) of possible changes in the internal energy of the system due to the process.

$List-I$	$List-II$
$(I)$ $10^{-3} \, kg$ of water at $100^{\circ} C$ is converted to steam at the same temperature, at a pressure of $10^5 \, Pa$. The volume of the system changes from $10^{-6} \, m^3$ to $10^{-3} \, m^3$. Latent heat of water $= 2250 \, kJ/kg$.	$(P)$ $2 \, kJ$
$(II)$ $0.2 \, moles$ of a rigid diatomic ideal gas with volume $V$ at temperature $500 \, K$ undergoes an isobaric expansion to volume $3V$. Assume $R = 8.0 \, J \, mol^{-1} \, K^{-1}$.	$(Q)$ $7 \, kJ$
$(III)$ One mole of a monatomic ideal gas is compressed adiabatically from volume $V = 1/3 \, m^3$ and pressure $2 \, kPa$ to volume $V/8$.	$(R)$ $4 \, kJ$
$(IV)$ Three moles of a diatomic ideal gas whose molecules can vibrate, is given $9 \, kJ$ of heat and undergoes isobaric expansion.	$(S)$ $5 \, kJ$
	$(T)$ $3 \, kJ$

Which one of the following options is correct?