Which of the following sets of quantum numbers is not allowed?

An orbital with one angular node shows three maxima in its radial probability distribution curve, the orbital is

An element in $+2$ oxidation state has $24$ electrons. The atomic number of the element and the number of unpaired electrons in it respectively are

The orbital angular momentum of an electron in an $s$ orbital is

The angular part of the wave function for an orbital is given by $\psi_{(\theta, \phi)} = \left( \frac{15}{4\pi} \right)^{1/2} \sin \theta \cos \theta \sin \phi$,where $\theta$ is the angle from the $z$-axis. The angular node$(s)$ are:

Given below are two statements :
Statement $I$ : $A$ spectral line will be observed for a $2p_x \rightarrow 2p_y$ transition.
Statement $II$ : $2p_x$ and $2p_y$ are degenerate orbitals.
In the light of the above statements,choose the correct answer from the options given below :