Which of the following solutions does not act as a buffer $:-$

Given below are two statements:
Statement $I$: $A$ buffer solution is the mixture of a salt and an acid or a base mixed in any particular quantities.
Statement $II$: Blood is a naturally occurring buffer solution whose $pH$ is maintained by $H_2CO_3 / HCO_3^{-}$ concentrations.
In the light of the above statements,choose the correct answer from the options given below.

Calculate the $pH$ of a buffer solution containing $0.04 \ M$ $NaF$ and $0.02 \ M$ $HF$ $[pK_a = 3.142]$.

Under which condition does a basic buffer follow the equation $pOH - pK_b = 1$?

Find the value of $\frac{[NaCN]}{[HCN]}$ given the $pH$ of the buffer solution of $NaCN$ and $HCN$ is $9.3$ and $K_a$ of $HCN$ is $5 \times 10^{-10}$.

$A$ buffer solution contains $100 \ mL$ of $0.01 \ M \ CH_3COOH$ and $200 \ mL$ of $0.02 \ M \ CH_3COONa$. If $700 \ mL$ of $1 \ M \ NaCl$ is added,what are the $pH$ values before and after the addition? $(pK_a = 4.74)$