Which of the following statement is/are $TRUE$?

$A$ mixture $X$ containing $0.02 \ mol$ of $[Co(NH_3)_5SO_4]Br$ and $0.02 \ mol$ of $[Co(NH_3)_5Br]SO_4$ was prepared in $2 \ L$ of solution.
$1 \ L$ of mixture $X +$ excess $AgNO_3 \to Y$.
$1 \ L$ of mixture $X +$ excess $BaCl_2 \to Z$.
The number of moles of $Y$ and $Z$ are:

When a metal rod $M$ is dipped into an aqueous colourless concentrated solution of compound $N$,the solution turns light blue. Addition of aqueous $NaCl$ to the blue solution gives a white precipitate $O$. Addition of aqueous $NH_3$ dissolves $O$ and gives an intense blue solution.
$1.$ The metal rod $M$ is
$(A)$ $Fe$ $(B)$ $Cu$ $(C)$ $Ni$ $(D)$ $Co$
$2.$ The compound $N$ is
$(A)$ $AgNO_3$ $(B)$ $Zn(NO_3)_2$
$(C)$ $Al(NO_3)_3$ $(D)$ $Pb(NO_3)_2$
$3.$ The final solution contains
$(A)$ $[Pb(NH_3)_4]^{2+}$ and $[CoCl_4]^{2-}$
$(B)$ $[Al(NH_3)_4]^{3+}$ and $[Cu(NH_3)_4]^{2+}$
$(C)$ $[Ag(NH_3)_2]^{+}$ and $[Cu(NH_3)_4]^{2+}$
$(D)$ $[Ag(NH_3)_2]^{+}$ and $[Ni(NH_3)_6]^{2+}$
Give the answer for questions $1$,$2$ and $3$.

In basic medium, the amount of $Ni^{2+}$ in a solution can be estimated with the dimethylglyoxime reagent. The correct statement$(s)$ about the reaction and the product is (are):

Match List-$I$ with List-$II$ and select the correct option:

List-$I$	List-$II$
$(A). [Ag(CN)_2]^-$	$1. \text{Square planar, } 1.73 \, B.M.$
$(B). [Cu(CN)_4]^{3-}$	$2. \text{Linear, } 0 \, B.M.$
$(C). [Cu(CN)_6]^{4-}$	$3. \text{Octahedral, } 0 \, B.M.$
$(D). [Cu(NH_3)_4]^{2+}$	$4. \text{Tetrahedral, } 0 \, B.M.$
$(E). [Fe(CN)_6]^{4-}$	$5. \text{Octahedral, } 1.73 \, B.M.$

Identify the correct set from the following table: