Which of the following statements is correct?

  • A
    At equilibrium,the concentration of reactants and products becomes constant because the forward and backward reactions continue at the same rate,not because they cease.
  • B
    Addition of a catalyst speeds up the forward and backward reactions to the same extent for any given reaction.
  • C
    The equilibrium constant of an exothermic reaction decreases with an increase in temperature.
  • D
    $K_p$ is always greater than $K_c$.

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What is heterogeneous equilibrium? Give its types with examples.

For the reaction $CH_4(g) + 2O_2(g) \rightleftharpoons CO_2(g) + 2H_2O(l)$,the enthalpy change is $\Delta H_r = -170.8 \, kJ \, mol^{-1}$. Which of the following statements is $NOT$ true?

Two solids dissociate as follows:
$A_{(s)} \rightleftharpoons B_{(g)} + C_{(g)}$; $K_{p_1} = x \, atm^2$
$D_{(s)} \rightleftharpoons C_{(g)} + E_{(g)}$; $K_{p_2} = y \, atm^2$
The total pressure when both the solids dissociate simultaneously is:

$5 \ \text{moles}$ of $SO_2$ and $5 \ \text{moles}$ of $O_2$ are allowed to react to form $SO_3$ in a closed vessel. At the equilibrium stage,$60\%$ of $SO_2$ is used up. The total number of moles of $SO_2$,$O_2$,and $SO_3$ in the vessel now is:

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Calculate the equilibrium constant for the reaction $H_{2(g)} + CO_{2(g)} \rightleftharpoons H_2O_{(g)} + CO_{(g)}$ at $1395 \ K$ by using the following data:
$2H_2O_{(g)} \rightleftharpoons 2H_{2(g)} + O_{2(g)}; K_1 = 2.1 \times 10^{-13}$
$2CO_{2(g)} \rightleftharpoons 2CO_{(g)} + O_{2(g)}; K_2 = 1.4 \times 10^{-12}$

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