Which of the following statement$(s)$ is (are) correct?

  • A
    The electronic configuration of $Cr$ is $[Ar] \ 3d^5 4s^1$ (Atomic no. of $Cr = 24$)
  • B
    The magnetic quantum number may have a negative value
  • C
    In silver atom,$23$ electrons have a spin of one type and $24$ of the opposite type (Atomic no. of $Ag = 47$)
  • D
    All of the above

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What is the ratio of time periods in the $3^{rd}$ orbit of $H^{-}$ atom to the $2^{nd}$ orbit of $He^{+}$ ion?

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Among the following,the correct statement$(s)$ for electrons in an atom is(are):
$A$. Uncertainty principle rules out the existence of definite paths for electrons.
$B$. The energy of an electron in $2s$ orbital of an atom is lower than the energy of an electron that is infinitely far away from the nucleus.
$C$. According to Bohr's model,the most negative energy value for an electron is given by $n=1$,which corresponds to the most stable orbit.
$D$. According to Bohr's model,the magnitude of velocity of electrons increases with increase in values of $n$.

Consider the following:
$I$. The electron spin quantum number describes the orientation of the spin of the nucleus with respect to the magnetic field.
$II$. The orbitals represented by the quantum numbers $n=3, l=2, m=+2$ and $n=3, l=2, m=-2$ have the same energy.
$III$. The energy of a photon is directly proportional to wavelength but inversely proportional to wave number.
$IV$. Lyman series of lines appear in ultra-violet region.
The correct statements are:

The wave function $\psi_{n, l, m_l}$ is a mathematical function whose value depends upon spherical polar coordinates $(r, \theta, \phi)$ of the electron and is characterized by the quantum numbers $n, l$ and $m_l$. Here $r$ is the distance from the nucleus,$\theta$ is the colatitude,and $\phi$ is the azimuth. In the mathematical functions given in the Table,$Z$ is the atomic number and $a_0$ is the Bohr radius.
Column-$I$ Column-$II$ Column-$III$
$I$. $1s$ orbital $i$. $\psi_{n, l, m_l} \propto (\frac{Z}{a_0})^{3/2} e^{-(Zr/a_0)}$ $P$. (Graph shown)
$II$. $2s$ orbital $ii$. One radial node $Q$. Probability density at nucleus $\propto 1/a_0^3$
$III$. $2p_z$ orbital $iii$. $\psi_{n, l, m_l} \propto (\frac{Z}{a_0})^{5/2} r e^{-(Zr/2a_0)} \cos \theta$ $R$. Probability density is maximum at nucleus
$IV$. $3d_{z^2}$ orbital $iv$. $xy$-plane is a nodal plane $S$. Energy needed to excite electron from $n=2$ state to $n=4$ state is $27/32$ times the energy needed to excite electron from $n=2$ state to $n=6$ state

$1$. For the given orbital in Column-$I$,the only $CORRECT$ combination for any hydrogen-like species is:
$[A] (IV)(iv)(R)$ $[B] (II)(ii)(P)$ $[C] (III)(iii)(P)$ $[D] (I)(ii)(S)$
$2$. For $He^{+}$ ion,the only $INCORRECT$ combination is:
$[A] (II)(ii)(Q)$ $[B] (I)(i)(S)$ $[C] (I)(i)(R)$ $[D] (I)(iii)(R)$
$3$. For the hydrogen atom,the only $CORRECT$ combination is:
$[A] (I)(iv)(R)$ $[B] (I)(i)(P)$ $[C] (II)(i)(Q)$ $[D] (I)(i)(S)$

Which of the following graphs represents one node?

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