Which of the following statements about aniline is false?

  • A
    $A$. Aniline is a stronger base than ammonia.
  • B
    $B$. Aniline is less basic than methylamine.
  • C
    $C$. $pK_b$ of aniline is more than that of ammonia.
  • D
    $D$. Aniline reacts with bromine water to form a white precipitate.

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Compound $III$ is
$\xrightarrow[{ii)\,CuCl/HCl}]{{i)\,HNO_2\,(0 - 5\,^oC)}}I$ $\xrightarrow{{Sn/HCl}}II$ $\xrightarrow[{ii)\,H_3PO_2 + H_2O}]{{i)HNO_2\,(0 - 5\,^oC)\,}}III$

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Consider the following reactions:
$[P] \xrightarrow[(i) \ NaNO_2/HCl, \ 0 - 5^oC]{(ii) \ \beta-naphthol/NaOH} \text{Colored Solid}$
$[P] \xrightarrow{Br_2/H_2O} C_7H_6NBr_3$
The compound $[P]$ is:

$RCONH_2$ is converted into $RNH_2$ by means of Hofmann bromamide degradation. In this reaction,$RCONHBr$ is formed from which this reaction has derived its name. Electron donating group at phenyl activates the reaction. Hofmann degradation reaction is an intramolecular reaction.
$1.$ How can the conversion of $(i)$ to $(ii)$ be brought about?
$(A)$ $KBr$
$(B)$ $KBr + CH_3ONa$
$(C)$ $KBr + KOH$
$(D)$ $Br_2 + KOH$
$2.$ Which is the rate determining step in Hofmann bromamide degradation?
$(A)$ Formation of $(i)$
$(B)$ Formation of $(ii)$
$(C)$ Formation of $(iii)$
$(D)$ Formation of $(iv)$
$3.$ What are the constituent amines formed when the mixture of $(i)$ and $(ii)$ undergoes Hofmann bromamide degradation?
Give the answer for question $1$,$2$,and $3$.

Total number of secondary amines (excluding stereoisomers) possible with the molecular formula $C_5H_{13}N$ is

In the sequence of the following reactions,$X$ and $Y$ are respectively: $CH_3OH$ $\xrightarrow{HI} CH_3I$ $\xrightarrow{KCN} CH_3CN$ $\xrightarrow{\text{reduction}} X$ $\xrightarrow{HNO_2} Y$

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