Which of the following statements are not correct?
$A$. For water, magnitude of $K_b$ is more than the magnitude of $K_f$.
$B$. The elevation in boiling point of water when a non-volatile solute is added to it is larger in magnitude than its depression in freezing point.
$C$. Osmotic pressure measurement is preferred over any other colligative property to determine molar mass of proteins and polymers.
$D$. The dimerised form of benzoic acid in benzene is $C_6H_5 - C(=O) - OH \cdots O = C(OH) - C_6H_5$. Choose the correct answer from the options given below:

  • A
    $A$ and $B$ only
  • B
    $A$ and $D$ only
  • C
    $A, B$ and $D$ only
  • D
    $A, C$ and $D$ only

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Similar Questions

Elevation in the boiling point for $1 \ m$ solution of glucose is $2 \ K$. The depression in the freezing point for $2 \ m$ solution of glucose in the same solvent is $2 \ K$. The relation between $K_b$ and $K_f$ is

$A$ non-volatile, non-electrolyte solid solute when dissolved in $40 \text{ g}$ of a solvent, the vapour pressure of the solvent decreased from $760 \text{ mm Hg}$ to $750 \text{ mm Hg}$. If the same solution boils at $320 \text{ K}$, then the number of moles of the solvent present in the solution is . . . . . . . (Nearest integer) [Given: boiling point of the pure solvent = $319.5 \text{ K}$, $K_b$ of the solvent = $0.3 \text{ K kg mol}^{-1}$]

$A$ solution of urea (molar mass $60 \, g \, mol^{-1}$) boils at $100.18 \, ^oC$ at atmospheric pressure. If $K_f$ and $K_b$ for water are $1.86$ and $0.512 \, K \, kg \, mol^{-1}$ respectively,the above solution will freeze at ........... $^oC$.

Column-$I$ (Various solutions)Column-$II$ (Their freezing point)
$a$. $0.1 \ M \ BaCl_2$ solution$p$. $271 \ K$
$b$. $0.1 \ M \ NaCl$ solution$q$. $270 \ K$
$c$. $0.1 \ M \ K_3[Fe(CN)_6]$ solution$s$. $269 \ K$
$d$. $0.1 \ M \ Al_2(SO_4)_3$ solution$r$. $268 \ K$
Given: Freezing point of $0.1 \ M$ sucrose solution $= 272 \ K$ and Freezing point of water $= 273 \ K$. Assume molarity $=$ molality. Which of the following options shows the correct matches?

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Assertion : If one component of a solution obeys Raoult's law over a certain range of composition,the other component will not obey Henry's law in that range.
Reason : Raoult's law is a special case of Henry's law.

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