Which of the following statements is correct about the heat of combustion?

While performing a thermodynamics experiment,a student made the following observations:
$HCl + NaOH \rightarrow NaCl + H_{2}O$ $\Delta H = -57.3 \ kJ \ mol^{-1}$
$CH_{3}COOH + NaOH \rightarrow CH_{3}COONa + H_{2}O$ $\Delta H = -55.3 \ kJ \ mol^{-1}$
The enthalpy of ionization of $CH_{3}COOH$ as calculated by the student is $kJ \ mol^{-1}$. (nearest integer)

Heat of combustion of two isomers $x$ and $y$ are $17 \ kJ/mol$ and $12 \ kJ/mol$ respectively. From this information,it may be concluded that:

Calculate the heat required to convert $9 \ g$ of liquid water to water vapor using the following equations:
$H_{2(g)} + 1/2 O_{2(g)} \longrightarrow H_2O_{(g)} \quad \Delta H = -57 \ kCal$
$H_{2(g)} + 1/2 O_{2(g)} \longrightarrow H_2O_{(l)} \quad \Delta H = -68.3 \ kCal$ (in $kCal$)

Calculate the enthalpy change of the reaction for $H_2(g) + Cl_2(g) \rightarrow 2HCl(g)$, given the bond energies (in $\text{kJ mol}^{-1}$): $H-H = 436$, $Cl-Cl = 242$, $H-Cl = 431$.

$S_{(g)} + \frac{3}{2} O_{2(g)} \rightarrow SO_{3(g)} + 2x \ kcal$
$SO_{2(g)} + \frac{1}{2} O_{2(g)} \rightarrow SO_{3(g)} + y \ kcal$
The heat of formation of $SO_{2(g)}$ is given by :