Which of the following statements is incorrect?

  • A
    For elementary reactions,the order of reaction and molecularity are identical.
  • B
    For the rate-determining step,the order and molecularity are identical.
  • C
    $A$ catalyst does not affect $\Delta H$ (heat of reaction) of a chemical reaction.
  • D
    The activation energy of a reaction decreases with an increase in temperature.

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For the process $R \rightarrow P$, the energy of the reactant is $50 \ kJ$ and the energy of the transition state is $170 \ kJ$. Determine the activation energy $(E_a)$ for the forward reaction in $kJ$.

The first order rate constant for the decomposition of $CaCO_3$ at $700 \ K$ is $6.36 \times 10^{-3} \ s^{-1}$ and activation energy is $209 \ kJ \ mol^{-1}$. Its rate constant (in $s^{-1}$) at $500 \ K$ is $x \times 10^{-6}$. The value of $x$ is ..... (Nearest integer)
Given $R=8.31 \ J \ K^{-1} \ mol^{-1} ; \log(6.36 \times 10^{-3})=-2.19 ; [10^{-4.79}=1.62 \times 10^{-5}]$

The Arrhenius equation is represented as $k = A e^{-E_a/RT}$. The activation energy $E_a$ of the reaction can be calculated by plotting:

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The rate constant for the decomposition of a hydrocarbon is given as $K = (4.5 \times 10^{11} \ s^{-1}) e^{-(28000 \ K) / T}$. The activation energy of the reaction (in $J/mol$) is:

The energy of activation is

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