Which of the following would produce a buffer solution when mixed in equal volumes?

Which of the following mixtures of solutions can function as a buffer solution?

Equal volumes of $0.5 \ N$ acetic acid and $0.5 \ N$ sodium acetate are mixed. What is the $pH$ of the resultant solution? $(pK_{a}$ of acetic acid $= 4.75)$

$A$ litre of buffer solution contains $0.1 \ mol$ of each of $NH_3$ and $NH_4Cl$. On the addition of $0.02 \ mol$ of $HCl$ by dissolving gaseous $HCl$,the $pH$ of the solution is found to be $...... \times 10^{-3}$ (Nearest integer).
Given: $pK_b(NH_3) = 4.745$,$\log 2 = 0.301$,$\log 3 = 0.477$,$T = 298 \ K$.

The $K_b$ of $NH_4OH$ is $1.8 \times 10^{-5}$. Calculate the $pH$ of a solution containing $0.15 \ M$ $NH_4OH$ and $0.25 \ M$ $NH_4Cl$.

$2 \ g$ acetic acid and $3 \ g$ sodium acetate are present in $100 \ mL$ aqueous solution. What will be the $pH$ of the solution if the ionisation constant of acetic acid is $1.8 \times 10^{-5}$?