Which one of the following electrolytes has the same value of van't Hoff factor $(i)$ as that of $Al_2(SO_4)_3$ (if all are $100 \%$ ionised)?

  • A
    $Al(NO_3)_3$
  • B
    $K_4[Fe(CN)_6]$
  • C
    $K_2SO_4$
  • D
    $K_3[Fe(CN)_6]$

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The degree of dissociation of $Ca(NO_3)_2$ in a dilute aqueous solution containing $7 \ g$ of the salt per $100 \ g$ of water at $100^{\circ}C$ is $70$ percent. If the vapour pressure of water at $100^{\circ}C$ is $760 \ mm \ Hg$,calculate the vapour pressure of the solution.

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The measured osmotic pressure of a solution prepared by dissolving $17.4 \ mg$ of $K_2SO_4$ in $2 \ L$ of water at $27^{\circ} C$ is $3.735 \times 10^{-3} \ bar$. The van't Hoff factor is $(R = 0.083 \ L \ bar \ K^{-1} \ mol^{-1}$; atomic weights $K = 39, S = 32, O = 16)$.

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The osmotic pressure of a dilute solution of an ionic compound $XY$ in water is four times that of a solution of $0.01\, M\, BaCl_2$ in water. Assuming complete dissociation of the given ionic compounds in water,the concentration of $XY$ (in $mol\, L^{-1}$) in solution is

An aqueous solution is prepared by dissolving $0.1 \ mol$ of an ionic salt in $1.8 \ kg$ of water at $35^{\circ} C$. The salt remains $90 \%$ dissociated in the solution. The vapour pressure of the solution is $59.724 \ mm \ Hg$. Vapor pressure of water at $35^{\circ} C$ is $60.000 \ mm \ Hg$. The number of ions present per formula unit of the ionic salt is . . . . . .

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