Which product would be expected to predominate in the given reaction?

Which of the following graphs represents the correct graph for $S_N1$ reaction?

Match the reactions in List-$I$ with the major products in List-$II$:
| List-$I$ | List-$II$ (Major Product) |
| :--- | :--- |
| $(A)$ $CH_3-CHBr-CH_2Br \xrightarrow{KOH/C_2H_5OH}$ | $(I)$ $1^{\circ}$-alkyl bromide |
| $(B)$ $CH_3-CH_2-CH=CH_2 \xrightarrow{HBr, (C_6H_5CO)_2O_2, \Delta}$ | $(II)$ $2^{\circ}$-alkyl bromide |
| $(C)$ $CH_3CH_2CH_3 \xrightarrow{Br_2, h\nu}$ | $(III)$ Allyl bromide |
| $(D)$ $CH_3-CH=CH_2 \xrightarrow{NBS, \Delta}$ | $(IV)$ Alkenyl bromide |

The products $(A)$ and $(B)$ respectively are:

Which one of the following compounds will be most reactive for $S_N1$ reactions?

Which of the following is $NOT$ obtained when a mixture of chloroethane and $1-$chloropropane is treated with sodium metal in dry ether?