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(D) The electronic configuration of $Ti^{3+}$ $(Z=22)$ is $[Ar] 3d^1$.In an octahedral crystal field,the $d$-orbitals split into $t_{2g}$ and $e_g$ se

Vedclass · Accepted Answer

$t_{2g}^1 e_g^0 \rightarrow t_{2g}^0 e_g^1$

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(D) The electronic configuration of $Ti^{3+}$ $(Z=22)$ is $[Ar] 3d^1$.In an octahedral crystal field,the $d$-orbitals split into $t_{2g}$ and $e_g$ sets.The single electron occupies the lower energy $t_{2g}$ orbital,giving the configuration $t_{2g}^1 e_g^0$.Upon absorbing visible light,the electron is excited to the higher energy $e_g$ orbital.Therefore,the electronic transition is $t_{2g}^1 e_g^0 \rightarrow t_{2g}^0 e_g^1$.

Which transition of electron will be observed in the following,when $Ti^{3+}$ ion having complex absorbs visible light of certain wavelength?

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