Write a note on Kolbe's reaction.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) Kolbe's reaction is a chemical reaction used to synthesize salicylic acid from phenol.
$1$. Phenol is treated with sodium hydroxide $(NaOH)$ to form sodium phenoxide.
$2$. Sodium phenoxide is then reacted with carbon dioxide $(CO_2)$ at a temperature of $398 \ K$ and a pressure of $4-7 \ bar$.
$3$. This leads to the formation of sodium salicylate,which upon acidification with concentrated hydrochloric acid $(HCl)$ yields salicylic acid ($2$-hydroxybenzoic acid).
Reaction sequence:
$C_6H_5OH + NaOH \rightarrow C_6H_5ONa + H_2O$
$C_6H_5ONa + CO_2 \xrightarrow{398 \ K, 4-7 \ bar} C_6H_4(OH)COONa$
$C_6H_4(OH)COONa + H^+ \rightarrow C_6H_4(OH)COOH$ (Salicylic acid)

Explore More

Similar Questions

Assertion: Phenol undergoes Kolbe reaction,ethanol does not.
Reason: Phenoxide ion is more basic than ethoxide ion.

Which product is obtained when chlorobenzene is reacted with $6-8\%$ aqueous $NaOH$ at $633\,K$ temperature and $300\,bar$ pressure in the presence of an acid catalyst?

Difficult
View Solution

Which one of the following phenols does not give colour when condensed with phthalic anhydride in the presence of conc. $H_2SO_4$?

In the Liebermann’s nitroso reaction,the changes in the colour of phenol occur as:

Among $I, II, III$ (Phenol,o-nitrophenol,and p-nitrophenol respectively),the boiling point follows the order:

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo