Write a note on the standard hydrogen electrode $(SHE)$.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) According to the convention,a half-cell called the standard hydrogen electrode $(SHE)$,represented by $Pt_{(s)} | H_{2_{(g)}} (1 \ bar) | H^{+}_{(aq)} (1 \ M)$,is assigned a zero potential at all temperatures.
Construction of hydrogen electrode:
The standard hydrogen electrode consists of a platinum electrode coated with platinum black. The electrode is dipped in an acidic solution,and pure hydrogen gas is bubbled through it at $1 \ bar$ pressure.
The concentration of hydrogen ions in the solution is maintained at $1 \ M$.
The half-cell reactions are:
Oxidation: $\frac{1}{2} H_{2_{(g)}} \longrightarrow H^{+}_{(aq)} + e^{-}$
Reduction: $H^{+}_{(aq)} + e^{-} \longrightarrow \frac{1}{2} H_{2_{(g)}}$
Uses:
The standard hydrogen electrode is used as a reference electrode to measure the electrode potential of any other half-cell. By constructing a galvanic cell with the $SHE$ and another electrode,the measured cell potential at $298 \ K$ directly gives the potential of that half-cell,as the potential of the $SHE$ is taken as zero.

Explore More

Similar Questions

What will happen when a silver ring is placed in an acidic solution?

Reduction potential of ions are given below:
$ClO_4^{-}$ $E^{\circ} = 1.19 \ V$
$IO_4^{-}$ $E^{\circ} = 1.65 \ V$
$BrO_4^{-}$ $E^{\circ} = 1.74 \ V$

The correct order of their oxidising power is:

The values of $E^0$ for metals $A$,$B$,and $C$ are $0.34 \ V$,$-0.80 \ V$,and $-0.46 \ V$ respectively. State the correct order for their ability to act as reducing agents.

Calculate $E_{\text{cell}}^{\circ}$ for $Cd_{(s)}|Cd^{2+}_{(1M)}||Ag^{+}_{(1M)}|Ag_{(s)}$. Given: $E^{\circ}_{Cd^{2+}/Cd} = -0.403 \ V$ and $E^{\circ}_{Ag^{+}/Ag} = 0.799 \ V$. (in $V$)

Assertion : $Cu^{2+}$ ions get reduced more easily than $H^{+}$ ions.
Reason : Standard electrode potential of copper is $0.34 \ V$.

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo