Wurtz reaction of bromoethane gives $n$-butane. Sodium salt of $X$ on heating with sodalime also results in $n$-butane. Compound $X$ is

Identify the correct statements from the following:
$(i)$ Petrol and $CNG$ operated automobiles cause less pollution.
$(ii)$ Alkanes having tertiary hydrogen can be oxidised to alcohols by $KMnO_4$.
$(iii)$ Methane can be prepared by Kolbe's electrolytic method.
$(iv)$ Alkyl chloride on reduction with zinc and dilute hydrochloric acid gives alkane.

Least hindered rotation about carbon-carbon bond is observed in

What is the difference in molar mass of Undecane and Dodecane?

Which of the following has the highest boiling point?

Select the chain propagation steps in the free-radical chlorination of methane.
$(1) \, Cl_2 \to 2Cl^{\bullet}$
$(2) \, Cl^{\bullet} + CH_4 \to CH_3Cl + H^{\bullet}$
$(3) \, Cl^{\bullet} + CH_4 \to CH_3^{\bullet} + HCl$
$(4) \, H^{\bullet} + Cl_2 \to HCl + Cl^{\bullet}$
$(5) \, CH_3^{\bullet} + Cl_2 \to CH_3Cl + Cl^{\bullet}$