Arrange the following reactants in increasing order of reactivity towards $S_{N^1}$ solvolysis reaction with methanol.

  • A
    $3 < 2 < 4 < 1$
  • B
    $2 < 3 < 4 < 1$
  • C
    $4 < 3 < 2 < 1$
  • D
    $2 < 4 < 3 < 1$

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Which of the following statements is incorrect?

Match the reactants in Column-$(I)$ with the products formed in Column-$(II)$.
Column-$(I)$ (Reactants)Column-$(II)$ (Major Products)
$(A)$ $C_6H_5CH_3 + X_2 \xrightarrow{Fe, \text{dark}}$$(i)$ $C_6H_5CH(Br)CH_3$
$(B)$ $C_6H_5NH_2 \xrightarrow{NaNO_2, HX, 273-278 \ K}$$(ii)$ $C_6H_5N_2^+X^-$
$(C)$ $C_6H_5N_2^+X^- \xrightarrow{Cu_2X_2}$$(iii)$ $p-X-C_6H_4CH_3 + o-X-C_6H_4CH_3$
$(D)$ $C_6H_5CH_2CH_3 \xrightarrow{Br_2, \Delta \text{ or } UV \text{ light}}$$(iv)$ $C_6H_5X$

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Product $A$ is

Given below are four compounds:
$(a)$ $n$-propyl chloride,
$(b)$ $iso$-propyl chloride,
$(c)$ $sec$-butyl chloride,
$(d)$ $neo$-pentyl chloride.
Percentage of carbon in the one which exhibits optical isomerism is:

Match the reactions given in Column-$I$ with their names in Column-$II$:
Column-$I$ (Reactants) Column-$II$ (Name)
$A$. $R-X + NaI \xrightarrow{\text{dry acetone}} R-I + NaX$ $i$. Electrophilic addition
$B$. $H_3C-Br + AgF \to H_3C-F + AgBr$ $ii$. Finkelstein reaction
$C$. $H_3C-CH_3 + Cl_2 \xrightarrow{hv} H_3C-CH_2Cl + HCl$ $iii$. Swarts reaction
$D$. $CH_2=CH_2 + Br_2 \to BrCH_2-CH_2Br$ $iv$. Free radical substitution

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