Calculate the osmotic pressure in $atm$ at $0\,^oC$ of a $0.18\, m$ aqueous solution of $KCl$ which has a freezing point of $-0.68\,^oC$. Assume the volume of the solution is equal to the volume of pure water. $(K_f = 1.86\,^oC\, m^{-1})$

Which one of the following statements is false?

Match List-$I$ with List-$II$

List-$I$	List-$II$
$A$. Solution of chloroform and acetone	$I$. Minimum boiling azeotrope
$B$. Solution of ethanol and water	$II$. Dimerizes
$C$. Solution of benzene and toluene	$III$. Maximum boiling azeotrope
$D$. Solution of acetic acid in benzene	$IV$. $\Delta V_{mix}=0$

Choose the correct answer from the options given below $:$

The specific heat of a certain substance is $0.86 \,J \,g^{-1} \,K^{-1}$. Assuming ideal solution behaviour,the energy required (in $J$) to heat $10 \,g$ of $1 \,molal$ of its aqueous solution from $300 \,K$ to $310 \,K$ is closest to $.... \,J$
[Given: Molar mass of the substance $= 58 \,g \,mol^{-1}$; specific heat of water $= 4.2 \,J \,g^{-1} \,K^{-1}$]

Two elements $A$ and $B$ form compounds having formula $AB_{2}$ and $AB_{4}$. When dissolved in $20 \ g$ of benzene $(C_{6}H_{6})$,$1 \ g$ of $AB_{2}$ lowers the freezing point by $2.3 \ K$ whereas $1.0 \ g$ of $AB_{4}$ lowers it by $1.3 \ K$. The molar depression constant for benzene is $5.1 \ K \ kg \ mol^{-1}$. Calculate atomic masses of $A$ and $B$.

$A$ solution of urea (molar mass $60 \ g \ mol^{-1}$) boils at $100.20^{\circ}C$ at atmospheric pressure. If $K_{f}$ and $K_{b}$ for water are $1.86$ and $0.512 \ K \ kg \ mol^{-1}$ respectively,the freezing point of the solution will be: