Which of the following is not a buffer solution?

$1 \times 10^{-3} \ \text{mole}$ of $HCl$ is added to a buffer solution made up of $0.01 \ \text{M}$ acetic acid and $0.01 \ \text{M}$ sodium acetate. The final $pH$ of the buffer will be (given, $pK_{a}$ of acetic acid is $4.75$ at $25^{\circ} \text{C}$)

$A$ buffer solution is prepared by mixing $0.2 \ M$ sodium acetate and $0.1 \ M$ acetic acid. If $pK_{a}$ for acetic acid is $4.7$,find the $pH$.

$A$ solution of formic acid is half-neutralized by the addition of a $KOH$ solution. If $K_a (HCOOH) = 2 \times 10^{-4}$,what is the $pH$ of the solution? (Given: $\log 2 = 0.3010$)

What is the $pH$ of a solution containing $50 \ mL$ each of $0.1 \ M$ sodium acetate and $0.01 \ M$ acetic acid (in $.5$)? $(pK_{a} \ CH_3COOH = 4.50)$

$A$ buffer solution with $pH = 9$ is to be prepared by mixing $NH_4Cl$ and $NH_4OH$. Calculate the number of moles of $NH_4Cl$ that should be added to one litre of $1.0 \ M \ NH_4OH$. $[K_b = 1.8 \times 10^{-5}]$