From the following data,the enthalpy of dilution of $KCl$ will be ............ $kJ$.
$KCl_{(s)} + 20H_2O \to KCl(20H_2O); \Delta H = + 15.90 \ kJ$
$KCl_{(s)} + 200H_2O \to KCl(200H_2O); \Delta H = + 18.58 \ kJ$

Identify the correct statements from the following:
$I$. $\Delta_{r} G$ is zero for $A \rightleftharpoons B$ reaction.
$II$. The entropy of pure crystalline solids approaches zero as the temperature approaches absolute zero.
$III$. $\Delta U$ of a reaction can be determined using a bomb calorimeter.

Assertion : The increase in internal energy $(\Delta E)$ for the vaporization of one mole of water at $1 \ atm$ and $373 \ K$ is zero.
Reason : For all isothermal processes,$\Delta E = 0$.

If standard molar enthalpy change and standard molar internal energy change measured in a bomb calorimeter are equal,which one of the following statements is correct?

At $27 \, ^oC$,one mole of an ideal gas is compressed isothermally and reversibly from a pressure of $2 \ atm$ to $10 \ atm$. The values of $\Delta E$ and $q$ are $(R = 2 \ cal \ K^{-1} \ mol^{-1})$:

Calculate the work done in $J$ when $63.50 \ g$ of $Zn$ is dissolved in an open beaker with hydrochloric acid at $300 \ K$. (Atomic mass of $Zn = 63.5 \ amu$)