If standard molar enthalpy change and standard molar internal energy change measured in a bomb calorimeter are equal,which one of the following statements is correct?

Enthalpy of sublimation of iodine is $24 \ cal \ g^{-1}$ at $200 \ ^oC$. If specific heat of $I_{2(s)}$ and $I_{2(vap)}$ are $0.055$ and $0.031 \ cal \ g^{-1} K^{-1}$ respectively,then enthalpy of sublimation of iodine at $250 \ ^oC$ in $cal \ g^{-1}$ is

Arrange the following in order of magnitude of work done by the system / on the system at constant temperature:
$(a)$ $|w_{reversible}|$ for expansion in infinite stage.
$(b)$ $|w_{irreversible}|$ for expansion in single stage.
$(c)$ $|w_{reversible}|$ for compression in infinite stage.
$(d)$ $|w_{irreversible}|$ for compression in single stage.
Choose the correct answer from the options given below:

In which of the following processes does entropy increase?

Enthalpy of hydrogenation of one mole of benzene to cyclohexane is
$[$Resonance energy of benzene $= -150.4 \ kJ / mol$.
Enthalpy of hydrogenation of cyclohexene $= -119.5 \ kJ / mol$ $]$

The heats of combustion $\Delta H$ of $CH_4$,$C_2H_6$,$C_2H_4$,and $C_2H_2$ gases are $-212.8$,$-373.0$,$-337.0$,and $-310.5 \ kcal$ respectively at the same temperature. Which of these gases is the best fuel?