State the limitation of the second law of thermodynamics.

  • A
    It does not predict the direction of the reaction.
  • B
    It does not provide information about the rate of chemical reactions.
  • C
    It does not explain the conservation of energy.
  • D
    It is not applicable to closed systems.

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The entropy change involved in the isothermal reversible expansion of $2 \, \text{mole}$ of an ideal gas from a volume of $10 \, dm^3$ to a volume of $100 \, dm^3$ at $27 \, ^oC$ is : .............. $J \, K^{-1}$

The enthalpy of vaporisation of a liquid is $30 \ kJ \ mol^{-1}$ and entropy of vaporisation is $75 \ J \ K^{-1} \ mol^{-1}$. Calculate the boiling point of the liquid at $1 \ atm$. (in $K$)

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