Solid $NH_4HS$ is placed in a flask containing $NH_3$ gas at a certain temperature and a pressure of $0.50 \ atm$. The $NH_4HS$ decomposes to form $NH_3$ gas and $H_2S$ gas. When equilibrium is established in the flask,the total pressure increases to $0.84 \ atm$. What is the equilibrium constant $(K_p)$ for the decomposition of $NH_4HS$ at this temperature?

In a closed vessel at $448^{\circ} C$,$0.5 \ mol$ of $H_2$ and $0.5 \ mol$ of $I_2$ react to form hydrogen iodide.
Reaction: $H_{2(g)} + I_{2(g)} \rightleftharpoons 2HI_{(g)}$,$K_c = 50$.
$(i)$ Calculate the moles of $I_2$ that remain unreacted at equilibrium.
$(ii)$ Calculate $K_p$.

$2SO_2 + O_2 \to$ product. If the pressure of the reaction increases $3$ times, then the rate will be (in $\times$)?

For a reaction,$A \rightleftharpoons P$,the plots of $[A]$ and $[P]$ with time at temperatures $T_1$ and $T_2$ are given below. If $T_2 > T_1$,the correct statement$(s)$ is (are) (Assume $\Delta H^{\ominus}$ and $\Delta S^{\ominus}$ are independent of temperature and ratio of $\ln K$ at $T_1$ to $\ln K$ at $T_2$ is greater than $T_2 / T_1$. Here $H, S, G$ and $K$ are enthalpy,entropy,Gibbs energy and equilibrium constant,respectively.)
$(A)$ $\Delta H^{\ominus} < 0, \Delta S^{\ominus} < 0$
$(B)$ $\Delta G^{\ominus} < 0, \Delta H^{\ominus} > 0$
$(C)$ $\Delta G^{\ominus} < 0, \Delta S^{\ominus} < 0$
$(D)$ $\Delta G^{\ominus} < 0, \Delta S^{\ominus} > 0$

In reaction $A + 2B \rightleftharpoons 2C + D$,the initial concentration of $B$ was $1.5$ times that of $[A]$,but at equilibrium,the concentrations of $A$ and $B$ became equal. The equilibrium constant for the reaction is:

$PCl_{5} \rightleftharpoons PCl_{3} + Cl_{2} \quad K_{c} = 1.844$
$3.0 \ \text{moles}$ of $PCl_{5}$ is introduced in a $1 \ \text{L}$ closed reaction vessel at $380 \ \text{K}$. The number of moles of $PCl_{5}$ at equilibrium is $..... \times 10^{-3}$. (Round off to the Nearest Integer)