For a reaction,$A \rightleftharpoons P$,the plots of $[A]$ and $[P]$ with time at temperatures $T_1$ and $T_2$ are given below. If $T_2 > T_1$,the correct statement$(s)$ is (are) (Assume $\Delta H^{\ominus}$ and $\Delta S^{\ominus}$ are independent of temperature and ratio of $\ln K$ at $T_1$ to $\ln K$ at $T_2$ is greater than $T_2 / T_1$. Here $H, S, G$ and $K$ are enthalpy,entropy,Gibbs energy and equilibrium constant,respectively.)
$(A)$ $\Delta H^{\ominus} < 0, \Delta S^{\ominus} < 0$
$(B)$ $\Delta G^{\ominus} < 0, \Delta H^{\ominus} > 0$
$(C)$ $\Delta G^{\ominus} < 0, \Delta S^{\ominus} < 0$
$(D)$ $\Delta G^{\ominus} < 0, \Delta S^{\ominus} > 0$
$(A)$ $\Delta H^{\ominus} < 0, \Delta S^{\ominus} < 0$
$(B)$ $\Delta G^{\ominus} < 0, \Delta H^{\ominus} > 0$
$(C)$ $\Delta G^{\ominus} < 0, \Delta S^{\ominus} < 0$
$(D)$ $\Delta G^{\ominus} < 0, \Delta S^{\ominus} > 0$
- A$A, B$
- B$A, C$
- C$A, D$
- D$A, B, C$
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View SolutionFor the reaction $N_2 + 3H_2 \rightleftharpoons 2NH_3$,what is the relationship between $\Delta H$ and $\Delta E$?
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$X \rightleftharpoons Y + Z$ --- $(1)$
$A \rightleftharpoons 2B$ --- $(2)$
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$A \rightleftharpoons 2B$ --- $(2)$
are in the ratio of $9 : 1$. If the degree of dissociation of $X$ and $A$ is equal,then the total pressure at equilibrium for $(1)$ and $(2)$ are in the ratio:
Difficult
View SolutionDihydrogen gas is obtained from natural gas by partial oxidation with steam as per the following endothermic reaction:
$CH_{4(g)} + H_2O_{(g)} \rightleftharpoons CO_{(g)} + 3H_{2(g)}$
$(a)$ Write an expression for $K_p$ for the above reaction.
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$(i)$ increasing the pressure
$(ii)$ increasing the temperature
$(iii)$ using a catalyst?
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$(a)$ Write an expression for $K_p$ for the above reaction.
$(b)$ How will the values of $K_p$ and the composition of the equilibrium mixture be affected by:
$(i)$ increasing the pressure
$(ii)$ increasing the temperature
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$CaCO_{3(s)} \rightleftharpoons CaO_{(s)} + CO_{2(g)}$
For this equilibrium,the correct statement$(s)$ is (are):
$(A)$ $\Delta H$ is dependent on $T$
$(B)$ $K$ is independent of the initial amount of $CaCO_{3}$
$(C)$ $K$ is dependent on the pressure of $CO_{2}$ at a given $T$
$(D)$ $\Delta H$ is independent of the catalyst,if any
$CaCO_{3(s)} \rightleftharpoons CaO_{(s)} + CO_{2(g)}$
For this equilibrium,the correct statement$(s)$ is (are):
$(A)$ $\Delta H$ is dependent on $T$
$(B)$ $K$ is independent of the initial amount of $CaCO_{3}$
$(C)$ $K$ is dependent on the pressure of $CO_{2}$ at a given $T$
$(D)$ $\Delta H$ is independent of the catalyst,if any
DifficultIIT 2013
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