For the reaction $N_2 + 3H_2 \rightleftharpoons 2NH_3$,what is the relationship between $\Delta H$ and $\Delta E$?

The variation of equilibrium constant with temperature is given below:

$T_{1} = 25^{\circ}C$	$K_{1} = 100$
$T_{2} = 100^{\circ}C$	$K_{2} = 100$

The values of $\Delta H^{\circ}$,$\Delta G^{\circ}$ at $T_{1}$ and $\Delta G^{\circ}$ at $T_{2}$ (in $kJ \ mol^{-1}$) respectively,are close to: [Use $R = 8.314 \ J \ K^{-1} \ mol^{-1}$]

At $67\,^{\circ}C$ and $1\ bar$ pressure,dinitrogen tetraoxide is $50\%$ dissociated into nitrogen dioxide. $\Delta G^{\circ}$ for the process $N_2O_{4(g)} \rightleftharpoons 2NO_{2(g)}$ is $(R = \frac{25}{3} \ J \ K^{-1} \ mol^{-1}, \ln 2 = 0.7, \ln 3 = 1.1)$.

Solid $NH_4HS$ is placed in a flask containing $NH_3$ gas at a certain temperature and a pressure of $0.50 \ atm$. The $NH_4HS$ decomposes to form $NH_3$ gas and $H_2S$ gas. When equilibrium is established in the flask,the total pressure increases to $0.84 \ atm$. What is the equilibrium constant $(K_p)$ for the decomposition of $NH_4HS$ at this temperature?

The equilibrium constants $K_{p1}$ and $K_{p2}$ for the reactions $X \rightleftharpoons 2Y$ and $Z \rightleftharpoons P + Q$ respectively are in the ratio of $1 : 9$. If the degree of dissociation of $X$ and $Z$ be equal,then the ratio of total pressures at these equilibria is:

For the reaction $X_{(g)} + Y_{(g)} \rightleftharpoons Z_{(g)}$ at $550 \ K$,the value of $K_c$ is $10^{-4} \ mol^{-1} \ L$. If at equilibrium $[X] = \frac{1}{2}[Y] = \frac{1}{2}[Z]$,then the value of $[Z]$ at equilibrium will be: