$4-$methylbenzene sulphonic acid reacts with sodium acetate to give:

$(i) \ F_3CCOOH$
$(ii) \ CH_3COOH$
$(iii) \ C_6H_5COOH$
$(iv) \ CH_3CH_2COOH$
Correct order of $pK_a$ value is:

$CH_3COOH \xrightarrow{LiAlH_4} A$
$A + CH_3COOH \xrightarrow{H_3O^+} B + H_2O$
In the above reactions,'$A$' and '$B$' respectively are:

Given below are two statements:
Statement $I:$ Ethyl pent$-4-$yn$-$oate on reaction with $CH_{3}MgBr$ gives a $3^{\circ}$ alcohol.
Statement $II:$ In this reaction,one mole of ethyl pent$-4-$yn$-$oate utilizes two moles of $CH_{3}MgBr$.
In the light of the above statements,choose the most appropriate answer from the options given below:

Maximum enol content is in

Saponification (basic hydrolysis) of $C_6H_5-CO-^{18}OCH_3$ will yield. [$^{18}O$ = mass $-18$ isotope of oxygen]